Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Infrared Spectroscopic Study of Enol and Enol Derivatives Coordinated to Platinum(II) and Palladmm(II)
Yasuo WakatsukiShun-ichi Nozakurahunsuke Murahashi
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1971 Volume 44 Issue 3 Pages 786-791

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Abstract

The infrared spectra of [Cl2M Olefin]2 (olefin=vinyl alcohol, vinyl ethers, and their derivatives, M=Pt and Pd) have been studied in the 4000–100 cm−1 frequency region. A normal coordinate analysis of the coordinated vinyl alcohol indicated that the lone-pair electrons of oxygen conjugated with π-electrons of the double bond to some extent, even in the coordinated state. The coordination strengths of vinyl alcohol, vinyl ethers, and their derivatives have been examined by comparing the metal-olefin streching vibrations.

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