1972 Volume 45 Issue 7 Pages 2003-2006
The oxidation of styryl acetate, vinyl acetate, vinyl propionate, methyl acrylate, and methyl cinnamate with RhCl(PPh3)3 catalyst has been studied. The reaction is remarkably affected by the substituent on an olefinic carbon atom. The oxidation mechanism was discussed in connection with decarbonylation.
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