Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Oxidation by Transition Metal Complexes. V. Oxidation of Vinyl Esters Catalyzed by Rhodium Complex.
Kiyotomi TakaoHiromichi AzumaYuzo FujiwaraToshinobu ImanakaShiichiro Teranishi
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1972 Volume 45 Issue 7 Pages 2003-2006

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Abstract

The oxidation of styryl acetate, vinyl acetate, vinyl propionate, methyl acrylate, and methyl cinnamate with RhCl(PPh3)3 catalyst has been studied. The reaction is remarkably affected by the substituent on an olefinic carbon atom. The oxidation mechanism was discussed in connection with decarbonylation.

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