Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Low-frequency Lattice Vibrations and Intermolecular Forces of the 9,10-Anthraquinone Crystal
Yoshio MiyazakiMitsuo Ito
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1973 Volume 46 Issue 1 Pages 103-106

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Abstract

The low-frequency Raman active lattice vibrations of the 9,10-anthraquinone single crystal were measured at various temperatures from 26°C to −190°C, and the symmetry species of the observed Raman bands were determined by polarization measurements. From a comparison between the observed and calculated frequencies, it seems that Dashevsky’s potential expresses well the intermolecular potential of the 9,10-anthraquinone crystal. It was also found that the temperature dependence of lattice vibrations can be explained reasonably with this potential.

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