Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Catalytic Diacetoxylation of Dihaloethylenes in the Presence of Palladium Salts
Masahiro YamajiYuzo FujiwaraRyuzo AsanoShiichiro Teranishi
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1973 Volume 46 Issue 1 Pages 90-93

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Abstract

The reaction of dihaloethylenes with acetate anions in the presence of palladium(II) salts gave trans-diacetoxyethylenes catalytically. It was found that the system, PdCl2–NaOAc–CH3CN is the best for the diacetoxylation of dihaloethylenes, and that palladium(II) salts catalyze the isomerization of trans-diacetoxyethylene to its 1,1-diacetoxy derivative. The mechanism was also discussed.

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