Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Crystal Structure of an N-Methylphenothiazine–7,7,8,8-Tetracyanoquinodimethane Complex, N-MePZT–TCNQ
Hayao Kobayashi
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1973 Volume 46 Issue 10 Pages 2945-2949

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Abstract

Crystals of the 1 : 1 charge-transfer complex of N-MePZT–TCNQ, are monoclinic with those lattice constants: a=10.904, b=13.321, c=7.086 Å, and β=91.06°, and with the space group C2/m. X-ray structure analysis showed that the mixed-stacks of N-MePZT and TCNQ, exist along the c axis. N-MePZT is disordered, and its apparent molecular symmetry is C2h, taking four possible conformations. The molecular geometry of TCNQ, indicates that the amount of the charge transferred from N-MePZT is very small (<0.2e).

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