Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Kinetic Studies of the Nickel Lactate Complex Formation in Solution by the Pressure-jump Method
Shoji HaradaHideyuki TanabeTatsuya Yasunaga
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1973 Volume 46 Issue 10 Pages 3125-3127

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Abstract

The nickel lactate complex formation reaction in an aqueous solution was studied by the pressure-jump method and the overall rate constants, the stability constants, and the activation parameters were determined. The results were interpreted by the use of the step-by-step complex formation mechanism, and it was revealed that the rate-determining step is the chelate-ring formation process. The ligand effect on the rate of the complex formation was also considered.

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