Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Catalytic Effect of Bases on the O→N Migration of the s-Triazinyl Group in O-(s-Triazinyl)-2-aminophenols
Takeo ShiojimaYoji HashidaKohji Matsui
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1973 Volume 46 Issue 10 Pages 3147-3150

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Abstract

The catalytic effect of bases on the O→N migration of the s-triazinyl group in O-(s-triazinyl)-2-aminophenols has been studied kinetically. In the rearrangement of N-(acyl)-O-(s-triazinyl)-2-aminophenols (II) in alkaline aqueous methanol, the reactive species was found to be an ion formed by the ionization of the acylamino group. In the case of O-(s-triazinyl)-2-aminophenols (I), the rearrangement was subjected to a general base catalysis, although the extent was small.

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