Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
The Methylenation of Several Allylbenzene-1,2-diol Derivatives in Aprotic Polar Solvents
Harushige FujitaMasataro Yamashita
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1973 Volume 46 Issue 11 Pages 3553-3554

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Abstract

The aprotic polar solvents, such as DMF (N,N-dimethylformamide) and DMSO (dimethyl sulfoxide), accelerated very effectively the methylenation of 1,2-dihydroxy-4- (I), 1,2-dihydroxy-3,4-dimethoxy-5- (II), and 1,2-dihydroxy-3-methoxy-5-allylbenzene (III) in the presence of bronze and cupric oxide as catalysts.

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