Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Intensity in the Resonance Raman Effect. I. The Diatomic Molecule in the Harmonic Potential Approximation
Shunsuke Kobinata
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1973 Volume 46 Issue 12 Pages 3636-3640


The formulas for the Raman intensities of fundamental and n-th overtones were investigated theoretically, starting from the Kramers-Heisenberg dispersion formula and referring to a diatomic molecule in a harmonic potential approximation. The derived formulas were then applied to fifteen overtone bands of iodine, which have been observed in gas, and to the exciting frequency dependence of the fundamental and the first overtone intensities of iodine in a CHCl3 solution. It was shown that the formulas quantitatively explain the trend of the observed data well.

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