Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
ESR of Copper(II) Complexes in Magnetically Non-dilute Crystals. I. Single Crystals of Bis(L-alaninato)copper(II)
Hiroshi YokoiShigeru Ohsawa
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1973 Volume 46 Issue 9 Pages 2766-2768


Single-crystal ESR studies have been carried out on bis(L-alaninato)copper(II). Only one symmetric absorption peak has been obtained in any direction of the magnetic field, regardless of the fact that there are two molecules per unit cell. The principal values and the directions of the principal axes of the g tensor have been determined, and a correlation between those components of the g tensor and the crystal structure has been confirmed on the basis of the effect of the spin-exchange interaction between the dissimilar copper(II) ions. The absorption linewidths have been examined in order to estimate the spin-exchange energy.

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