Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Reaction of Cycloalkanones with Copper(II) Halides. II. The Reaction of Cyclohexanones with Copper(II) Bromide
Kyoko NishizawaJ. Yasuo Satoh
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1975 Volume 48 Issue 6 Pages 1875-1877

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Abstract

The reaction of cyclohexanones with copper(II) bromide gave polybrominated cyclohexanediones in all cases except for the case of 3,5-dimethylcyclohexanone. Moreover, in this reaction, a pyrocatechol and a phenol derivative were obtained from 4-methyl- and 3,5-dimethylcyclohexanone respectively. The mechanism of this reaction was discussed.

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