Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Absolute Configurations and Chiroptical Properties of Optically Active Derivatives of Tricyclo[4.3.0.03,8]nonane (“Twist-brendane”)
Masao NakazakiKoichiro NaemuraSigeyuki Harita
Author information
JOURNALS FREE ACCESS

1975 Volume 48 Issue 6 Pages 1907-1913

Details
Abstract

(+)-Tricyclo[4.3.0.03,8]nonane (“twist-brendane”) was synthesized via (+)-tricyclo[4.3.0.03,8]nonan-9-one from (+)-endo-2-carboxybicyclo[2.2.2]oct-5-ene. Optically active derivatives of twist-brendane with two functional groups such as (−)-2,9-twist-brendanedione and (−)-9-methylenetwist-brendan-2-one were synthesized from (−)-endo-2-carboxybicyclo[2.2.2]oct-5-ene. Absolute configurations of the compounds were established and their chiroptical properties were discussed.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top