Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Preparation and Characterization of Isomers of (Amino acidato)(iminodiacetato)nitrocobaltate(III)(1–) Complexes
Yukihiro YamamotoSumio KaizakiYoichi Shimura
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1976 Volume 49 Issue 12 Pages 3540-3543

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Abstract

Three geometrical isomers of fac(ida)-[Co(NO2)(gly)(ida)] have been prepared and optically resolved (gly=glycinato(1–) and ida=iminodiacetato(2–) ligand), and their configurations were determined from the visible and ultraviolet absorption, and circular dichroism spectra. A diastereomeric pair was obtained for the corresponding L-alaninato, L-serinato, or L-prolinato complex.

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