Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
XPS Study on the Charge Distribution in Chromium(0) Complexes
Fumio KinomuraTadashi TamuraIwao WatanabeYu YokoyamaShigero Ikeda
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1976 Volume 49 Issue 12 Pages 3544-3547

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Abstract

Binding energies of core electrons in Cr(C6H6)2, Cr(C6H6)(CO)3, and Cr(CO)6 were measured by means of X-ray photoelectron spectroscopic method in solid phase. By comparison with their UPS spectra observed in gasous phase, binding energies referred to vacuum level can be obtained. On the basis of this result, charge distribution in these complexes are estimated. The intramolecular relaxation energy of Cr(C6H6)2 is also discussed.

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