Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Infrared and Mossbauer Spectra of Synthetic Garnets A3Fe2Si3O12 (A: Mn, Cd, Ca)
Hitoshi NishizawaMasahiko ShimadaKiyoshi MatsuokaMitsue Koizumi
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1977 Volume 50 Issue 12 Pages 3186-3188

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Abstract

The garnet Mn3Fe2Si3O12 with a0=11.821 Å was synthesized at high pressure and temperature. Infrared and Mossbauer spectra of the synthetic garnets A3Fe2Si3O12 (A: Mn, Cd, Ca) suggest that the distortion of SiO4 tetrahedra in these garnets increases and that of FeO6 octahedra decreases with increase in the radius of eight fold coordinated cation.

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