Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Structure and Reactions of Imidoyl Triphenylphosphonium Methylides
Hiroshi YoshidaTsuyoshi OgataSaburo Inokawa
Author information
JOURNALS FREE ACCESS

1977 Volume 50 Issue 12 Pages 3315-3319

Details
Abstract

Twenty-five imidoyl triphenylphosphonium methylides III were prepared from triphenylphosphonium methylide and imidoyl chlorides or imidates in moderate yields. The configration of these ylides was assigned on the basis of NMR spectroscopic studies. N-Tosyl substituted ylides showed no reactivity toward aldehydes, whereas N-aryl substituted ylides could be converted easily into α,β-unsaturated ketimines in good yields. The reaction of III with carbon disulfide was also studied.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top