Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Electronic Absorption and Fluorescence Spectra of [2.2]Anthracenophanes
Masaharu MoritaTohru KishiMasashi TanakaJiro TanakaJames FergusonYoshiteru SakataSoichi MisumiToyoharu HayashiNoboru Mataga
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1978 Volume 51 Issue 12 Pages 3449-3457

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Abstract

The absorption and the fluorescence spectra of four [2.2]anthracenophanes were investigated at low temperatures. A theoretical calculation of the energy levels was performed by including the charge resonance and the exciton type interactions. The fluorescence excitation polarization spectra were recorded for all absorption bands at low temperatures, the directions of the transition moment of the excimer type emission bands being estimated by the p-values and the established transition directions of anthracene chromophores. The assignments of the absorption bands are presented based on these results.

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