Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Activation of Carbon Dioxide by Tetraphenylporphinatoaluminium Methoxide. Reaction with Epoxide
Norikazu TakedaShohei Inoue
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1978 Volume 51 Issue 12 Pages 3564-3567

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Abstract

α,β,γ,δ-Tetraphenylporphinatoaluminium methoxide reacts reversibly with carbon dioxide in the presence of 1-methylimidazole, and this carbon dioxide is activated to react with propylene oxide to produce propylene carbonate under atmospheric pressure and at room temperature.

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