Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Vinyl Polymerization. 375. Radical Polymerization of Vinyl Monomer in Water Initiated with Tin Mercaptides and Iron(III) Ion
Yoshiaki NakamuraTatsuro OuchiMinoru Imoto
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1978 Volume 51 Issue 12 Pages 3574-3578

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Abstract

The polymerization of the vinyl monomer was carried out in water, using either dimethylbis(ethylthio)tin or triethyl(p-tolylthio)tin as an initiator. The polymerization required the coexistence of the iron(III) ion. The initiating species was concluded to be a thiyl radical. Macromolecular tin mercaptide was much more effective than monomeric tin mercaptide.

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