Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Oxidation of 2,5-Dimethoxyacetophenone Derivatives with Thallium(III) Nitrate in Trimethyl Orthoformate–Methanol. I
Kazuhiro MaruyamaTadashi Kozuka
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1978 Volume 51 Issue 12 Pages 3586-3589

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Abstract

Alkyl-substituted 2,5-dimethoxyacetophenones were oxidized with thallium(III) nitrate in methanol–trimethyl orthoformate (TMOF) to give methyl alkyl-substituted 2,5-dimethoxyphenylacetates in a good yield. A simple modification of separating method from the reacting mixture allowed us to obtain the corresponding methyl (alkylsubstituted 3,6-dioxo-1,4-cyclohexadienyl)acetates.

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