Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Requirements for an “Organic Metal”
Gunzi SaitoJohn P. Ferraris
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1980 Volume 53 Issue 8 Pages 2141-2145

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Abstract

Current theories on the origin of high electrical conductivity in TCNQ-based materials emphasize the need for incomplete charge transfer as well as segregated stacks of donor and acceptor molecules and uniform spacing within the stacks. The requirements for an “organic metal” are discussed in terms of partial charge transfer. An examination of 61 structurally related TTF–TCNQ, based complexes suggests that the combinations with the redox potential −0.02≤E1(D)−E1(A)≤0.34 V have a high possibility of being “organic metals.” A method to arrange the complex by the difference between the electrochemical half-wave potentials of the donor and the acceptor molecule is proposed to predict electrical properties of the complex.

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