Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Non-covalent Interactions in Metal Complexes. II. Induction of Asymmetry in Cobalt(III) Complexes with Amino Acid–Schiff Bases. Importance of CH···π-Interaction in Determining Configuration of Complexes
Hisashi OkawaYoshihiko NumataAyako MioSigeo Kida
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1980 Volume 53 Issue 8 Pages 2248-2251


Cobalt(III) complexes, [Co(l-mop=aa)2] and [Co(cop=aa)2] (aa=ala, val, leu, phe), where H2(l-mop=aa) and H2(cop=aa) denote amino acid-Schiff bases of l-menthyl 3-(o-hydroxybenzoyl)propionate and cholesteryl 3-(o-hydroxybenzoyl)propionate, respectively, were prepared in solution. The intensity of the CD peak induced at 520 nm changes with the solvent used for preparation of the complex, decreasing in the order: ethanol, methanol, dimethyl sulfoxide, N,N-dimethylformamide and acetonitrile. Since the order corresponds to the increasing order of the CH···π-interaction between the solvent and benzene, it seems that the CH···π-interaction between the chiral group and the aromatic nucleus in the ligand plays an important role in determining the configuration of the complexes.

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