Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Tetraammineplatinum(II)–Hydrogen Ion Exchange on α-Zirconium Phosphate and the Characterization of Its Complex Cation Form
Yoshitsugu HasegawaGiichi Yamamine
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1983 Volume 56 Issue 12 Pages 3765-3768

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Abstract

The tetraammineplatinum(II)–hydrogen-ion exchange on α-zirconium phosphate has been investigated. The ion-exchange process was examined by measuring the change in the pH values of the supernatants. α-Zirconium phosphate loaded with tetraammineplatinum(II) was characterized by means of chemical analysis, X-ray diffractometry, infrared spectroscopy, and thermal analysis. The ion-exchange reaction proceeded more easily than the hexaaminecobalt(III)–hydrogen-ion exchange, and about 50% of the hydrogen ions in α-zirconium phosphate were replaced by tetraammineplatinum(II). The interlayer distance of the exchanger expanded from 7.60 to 10.7 Å.

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