Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
A Chromatographic Study of the Acidic Hydrolysis of cyclo-Hexa- and cyclo-Octaphosphate
Genichiro Kura
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1983 Volume 56 Issue 12 Pages 3769-3772

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Abstract

The hydrolysis rate of inorganic cyclo-hexa- and cyclo-octaphosphate in 0.1 mol dm−3 HCl was determined by means of anion-exchange chromatography. The phosphorus content in the column effluent was determined automatically by the use of the MoV–MoVI reagent. The hydrolysis reactions were first-order. The rate constant decreases from cyclo- tri- to cyclo-hexaphosphate with the increased ring, however, that of cyclo-octaphosphate increases again. This increase is thought to be due to the stronger proton affinity of cyclo-octaphosphate. The Arrhenius activation energies for cyclo-hexa- and cyclo-octaphosphate hydrolysis were 91.5 and 96.9 kJ mol−1 respectively.

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