Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Effects of Salts on the Solubilities of Benzene, Toluene, Ethylbenzene, and Propylbenzene in Water
Isao SanemasaSeiji ArakawaMasatake ArakiToshio Deguchi
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1984 Volume 57 Issue 6 Pages 1539-1544

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Abstract

Salt effects on the solubilities of benzene, toluene, ethylbenzene, and propylbenzene were studied by making use of the solute vapor. The salting coefficients were determined at 25 °C, and the results were compared with the literature values and with those estimated by means of theoretical equations. The McDevit-Long equation did not give satisfactory predictions until the equation was multiplied by a factor of 0.4. The scaled particle theory gave a favorable agreement with the observations in most cases if suitable pair-potential parameters of solutes were used in the calculations.

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