Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Structure of Aquatris(m-hydroxybenzoato)cerium(III), [Ce(HOC6H4CO2)3(H2O)]n
Yukio KoizumiHiroshi SawaseYasuo SuzukiMamoru ShimoiAkira Ouchi
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1984 Volume 57 Issue 6 Pages 1677-1678

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Abstract

The crystal and molecular structure of the title complex has been determined by the use of the single-crystal X-ray diffraction method. The crystal of CeC21H17O10, F. W. 569.48, was monoclinic; space group P21c, a=13.401(2), b=19.173(5), c=8.079(1) Å, β=98.94(1)°, U=2050.6(8) Å3, Z=4, Dm=1.84(3), Dx=1.84 Mg m−3, and μ(Mo Kα)=2.31 mm−1. Each cerium(III) atom is ennea-coordinated and is in a tri-capped trigonal-prism geometry. They are in a linear polymer, and each cerium(III) atom is bridged to the next metal atom by three carboxylate ligands.

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