Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Syntheses and Circular Dichroism Studies of Oligopeptides Having Tri- or Tetra-L-prolyl Sequences
Kazuki SatoMasato TanakaTetsuo Hayase
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1984 Volume 57 Issue 6 Pages 1679-1680

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Abstract

CD spectra of many oligopeptides having tri- or tetra-L-prolyl sequences showed that a penta- or hexapeptide having a tetra-L-prolyl sequence took poly(L-proline) II helix irrespective of amino acid residues at N- or C-terminal of a L-prolyl cluster and that as to a size of the cluster, tri-L-prolyl sequence was enough to form the helix, when glycine was used as substituent.

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