Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Decomposition of t-Butyl Heptafluoroperoxybutyrate in Aromatic and Aliphatic Solvents
Hideo SawadaHidehiko HagiiKazuyoshi AoshimaMasato YoshidaMichio Kobayashi
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1985 Volume 58 Issue 12 Pages 3448-3452

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Abstract

Kinetical studies and products analyses of the thermal decomposition of t-butyl heptafluoroperoxybutyrate (TBH) in benzene, octane, nitrobenzene, pyridine, and methoxybenzene have been carried out. In benzene and octane, the decomposition appears to be entirely a radical process. In nitrobenzene and pyridine, the reactions are found to give ionic decomposition products exclusively. On the other hand, the decomposition of TBH in methoxybenzene is characteristic of mixed ionic and radical cleavages.

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