Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Internal Energy Distributions of NH(A3II). An Application of Phase Space Theory to the Electron-impact Dissociation
Ikuo TokueYoshio Ito
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1985 Volume 58 Issue 12 Pages 3480-3485

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Abstract

Internal energy distributions of NH(A) produced by electron impact on NH3, HN3, and HNCO are compared with those predicted by use of the phase space theory based on the method of Light and Pechukas. The values predicted under conservation of energy and total angular momentum are found to be inconsistent with the experimental results. The observed values are well simulated via the introduction of a nonstatistical bias by representing the selective coupling between the reaction coordinate and the rotational modes of the products. The dynamics for formation of NH(A) is discussed.

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