Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Absolute Configurations of Novel Axially Dissymmetric 10,10′-Dihydroxy-9,9′-biphenanthryl and Its Related Compounds
Koji YamamotoHitoshi FukushimaHiroya YumiokaMasao Nakazaki
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1985 Volume 58 Issue 12 Pages 3633-3634

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Abstract

Stereoselective oxidative coupling of 10-hydroxy-1,2,3,4-tetrahydrophenanthrene derived from methyl 3-methoxy-2-naphthoate gave (−)-(S)-10,10′-dihydroxy-1,1′,2,2′,3,3′,4,4′-octahydro-9,9′-biphenanthryl which was converted into (+)-(S)-10,10′-dimethoxy-9,9′-biphenanthryl assigning the S configuration to (−)-10,10′-dihydroxy-9,9′-biphenanthryl.

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