Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Synthesis and Magnetism of Trinuclear Copper(II) Complexes with a Salen-like Schiff Base and a Tertiary Diamine
Makoto HandaHisashi OkawaSigeo Kida
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JOURNALS FREE ACCESS

1985 Volume 58 Issue 6 Pages 1835-1836

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Abstract

Trinuclear Copper(II) complexes [{Cu(sb)}2Cu(da)](ClO4)2 have been synthesized by the use of a copper(II) complex with a salen analog ([Cu(sb)]) and a diamine (da) such as bpy or phen. Cryomagnetic investigations revealed the operation of an antiferromagnetic spin-exchange interaction (–J=26–78 cm−1) between the adjacent copper ions.

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