Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
A Fairly Effective Environment Substance [Co(sep)]3+ Ion in the Pfeiffer Effect of Some Oxalato Complexes of Chromium(III)
Katsuhiko MiyoshiYukio SakamotoYoshihisa TodaHayami Yoneda
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1985 Volume 58 Issue 6 Pages 1837-1838

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Abstract

A chiral complex ion [Co(sep)]3+ (sep=1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]eicosane) was found to displace the chiral equilibrium between Δ and Λ enantiomers greatly for moderately optically labile metal complexes [Cr(ox)2(acac)]2− and [Cr(ox)2(gly)]2− in dioxane–water mixtures.

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