Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Behavior of Trifluoroacetohydrazonoyl Bromide in Basic Media
Kiyoshi TanakaSeiji MaenoKeiryo Mitsuhashi
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1985 Volume 58 Issue 6 Pages 1841-1842

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Abstract

The bromide 1 was treated with sodium methoxide or phenoxide to give exclusively the corresponding substituted product. The predominant formation of the substituted products was also recognized with regard to various amines. However, the reaction with triethylamine proceeded more complicatedly to give the products via reduction process together with a trace amount of the dimer of N-phenyl-C-(trifluoromethyl)nitrilimine.

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