Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Dichlorotetrakis(isocyanide)dipalladium(I) Containing a Metal–Metal Bond
Yasuhiro YamamotoHiroshi Yamazaki
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1985 Volume 58 Issue 6 Pages 1843-1844

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Abstract

The structure of [{PdCl(t-BuNC)2}2] has been determined by X-ray diffraction. A metal–metal bond joins two Pd atoms, each of which possesses an essentially square-planar coordinate site. The photochemical reaction of [{PdCl(RNC)2}2] in CH2Cl2 led to a cleavage of the metal–metal bond to give trans-[PdCl2(t-BuNC)2].

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