Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Synthesis of Selenoxides by Oxidation of Selenides with t-Butyl Hypochlorite, and Its Application for Synthesis of Optically Active Selenoxide
Michio KobayashiHiromi OhkuboToshio Shimizu
Author information
JOURNALS FREE ACCESS

1986 Volume 59 Issue 2 Pages 503-506

Details
Abstract

An effective synthesis of selenoxides by the oxidation of selenides with t-butyl hypochlorite in the presence of methanol and pyridine followed by hydrolysis is descrived. This oxidation method is particularly effective for the oxidation of selenides which possess electron-withdrawing groups. A synthesis of partially optically active selenoxide with bulky substituents can be achieved using a novel oxidation method.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top