Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Novel Type of the Favorskii Rearrangement Combined with Aldol Reaction Leading to γ-Butyrolactone Derivatives
Takashi SakaiAkitoshi YamawakiTsuyoshi KatayamaHiroshi OkadaMasanori UtakaAkira Takeda
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1987 Volume 60 Issue 3 Pages 1067-1069

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Abstract

Reaction of Aromatic aldehydes or hetero-aromatic aldehydes with 3-chloro-3-methyl-2-butanone in ethanolic KOH at room temperature gave 3,3-dimethyl-5-aryltetrahydro-2-furanone as a major product. The reaction can be tentatively explained by the combination of Favorskii rearrangement and aldol reaction.

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