Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Formations of OH(X2II, A2Σ+) in the Reaction of NH(3Σ) with NO in Incident Shock Waves
Keiichi YokoyamaYasuo SakaneTakayuki Fueno
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1991 Volume 64 Issue 6 Pages 1738-1742

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Abstract

Gaseous mixtures of HNCO and NO diluted in Ar were heated by incident shock waves to about 3500 K to investigate the bimolecular reaction of NH(3Σ) with NO. Ultraviolet emissions from the excited NH(A3II) and OH(A2Σ+) were monitored to determine the rate constants for the ground-state reaction NH(3Σ)+NO→N2+OH(X2II). The branching ratio defined as the rate constant for the formation of OH relative to that for the NH(3Σ) decay was found to be 0.32±0.07 at the shock-wave temperature adopted. An intense spike of chemiluminescence due to OH(A2Σ+→X2II) was observed, a finding which indicates a possible participation of the channel NH(3Σ)+NO→N2+OH(A2Σ+) at high temperatures.

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