Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Photochemical Reactions of Aryl-Substituted Digermanes through a Pair of Organogermyl Radicals
Kunio MochidaMasanobu WakasaYoshio SakaguchiHisaharu Hayashi
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1991 Volume 64 Issue 6 Pages 1889-1895

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Abstract

The photochemical reactions of aryl-substituted digermanes were investigated by trapping experiments and a laser flash photolysis technique. The photolysis of phenylated digermanes resulted in germanium–germanium bond homolysis to give a pair of two germyl radicals. The germyl radicals abstracted a chlorine atom from carbon tetrachloride to give chlorogermanes. The pair of germyl radicals also underwent ipso-substitution, which was a precursor of the germylenes. The mechanism for the photochemistry of phenylated digermanes is discussed.

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