Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Spin-Trapping of Selenium-Containing Inorganic Radicals in Aqueous Solutions
Toshihiko OzawaAkira Hanaki
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1991 Volume 64 Issue 6 Pages 1976-1978

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Abstract

The selenite radical anion, SeO3\divdot, can be detected by ESR spectroscopy using water-soluble spin-traps, N-(4-pyridylmethylene)-t-butylamine N,N′-dioxide (POBN) and 3,5-dibromo-4-nitrosobenzenesulfonate (DBNBS), but selenate radical anion, SeO4\divdot, cannot be trapped by POBN or DBNBS.

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