Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Effects of Six-Membered Chelate Rings in the Oxidant Cobalt(III) Complexes on the Stereoselective Oxidation of [Co(en)3]2+
Akira TatehataHiromi Akita
Author information
JOURNALS FREE ACCESS

1991 Volume 64 Issue 6 Pages 1985-1987

Details
Abstract

The stereoselectivities in the oxidation of [Co(en)3]2+ by chiral cobalt(III) complexes containing six-membered chelate ligands, such as malonate, β-alaninate, and acetylacetonate ions, were examined. All of the oxidant complexes with the Δ-configuration studied here, like the corresponding oxalato and glycinato complexes containing five-membered chelate rings, led to an excess of Λ-[Co(en)3]3+, with the exception of Δ-[Co(ox)(acac)2].

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top