Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
CONCENTRATION CELL WITH TERNARY ELECTROLYTE
Kosaku Masaki
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1932 Volume 7 Issue 2 Pages 35-44

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Abstract

(1) The electromotive forces of the concentration cells with ternary electrolytes were studied by the three methods.
(a) At anion reversible cell with mercury electrode.
(b) At anion reversible cell with silver electrode.
(c) At the cation reversible cell with amalgam electrode.
(2) Several equations were theoretically obtained to calculate the electromotive forces of the cells above mentioned.
(3) Mobilities at 30°C. and activity coefficients of chlorine, zinc, calcium, barium, strontium and magnesium ions were calculated.
(4) We had a very good agreement between measured electromotive forces and calculated ones in the very dilute solutions.

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