分析化学
Print ISSN : 0525-1931
沃化第1蒼鉛トリフェニルセレノニウムの放射滴定による組成の決定
分析化学におけるオニウム化合物の適用に関する研究(第4報)
品川 睦明松尾 博吉田 光利
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ジャーナル フリー

1955 年 4 巻 3 号 p. 139-140

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Triphenylselenonium chloride, in the presence of iodide ion, reacts with bismuth ion to give a beautiful red orange precipitate. Various formulas had been proposed as to the composition of the precipitate, and at last, the authors were able to confirm its composition by application of polarography and a radioactive iodine, I131, imported from United States of America as follows : namely, bismuth ion and iodine ion were reacted at first to give a complex anion, BiI4-, and this was combined with triphenylselenonium ion, (C6H5)3 Se+, to form a precipitate of (C6H5)3 Se·BiI4.
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© The Japan Society for Analytical Chemistry
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