Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Intramolecular Interactions between Two Non-conjugated Metal Complex Moieties in Alkylene-bridged Ferrocene and (η-Cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III)
Takeo AkiyamaKosei NakamuraMasami TamadaHirobumi UshijimaMasatsugu KajitaniKunio ShimizuAkira Sugimori
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1990 Volume 19 Issue 8 Pages 1255-1258

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Abstract

Bimetallic complexes, A–CH2–B(1) and A–(CH2)2–B(2), were synthesized in which (η-cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III) (A) and ferrocene (B) moieties are bound at the cyclopentadienyl(cp) rings by–CH2–. Their cyclic voltammogramms show the presence of the intramolecular interaction between the two metal complex moieties, A and B. Moiety B (oxidized form) promotes decomposition of the oxidized form of A. The MS fragment patterns of 1 and 2 suggest the presence of a species in which two sulfur atoms of the dithiolene ligand bridge the two metal atoms.

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© 1990 The Chemical Society of Japan
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