Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
“Cone”–“Partial Cone” Isomerism in Tetramethoxy-p-t-butylcalix[4]arene. Novel Solvent Effects and Metal Template Effects
Seiji ShinkaiKoji IwamotoKoji ArakiTsutomu Matsuda
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1990 Volume 19 Issue 8 Pages 1263-1266

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Abstract

The solvent effects on the “cone”–“partial cone” equilibrium in tetramethoxy-p-t-butylcalix[4]arene were studied for the first time. It was found that the concentration of the “cone” isomer is increased with increasing solvent polarity. The shift in the equilibrium was accounted for by the differece in the dipole moment between “cone” and “partial cone” isomers.

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© 1990 The Chemical Society of Japan
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