Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Structural Characterization of the Transition-metal Imido Complex Coordinated in a Bidentate Fashion. Preparation and the Molecular Structure of Seven-Coordinate Hydrido(succinimido-N,O)bis[1,2-bis(dipehnylphosphino)ethane]molybdenum(II)
Susumu KurishimaTakashi Ito
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1990 Volume 19 Issue 8 Pages 1299-1302

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Abstract

The photoreaction of [MoH4(dppe)2] with succinimide gave [MoH(succinimido-N,O)(dppe)2], which was characterized spectroscopically as well as X-ray crystallographically to have the imido ligand coordinated to the metal bidentately via nitrogen and oxygen atoms constructing four membered metallacycle.

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© 1990 The Chemical Society of Japan
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