Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Photosensitized Isomerization of Hexamethyl(Dewar benzene) by Interactions with 1,4-Dicyanonaphthalene-Arene Exciplexes. An Adiabatic Triplex Pathway
Yasuhiro MasakiYoshikazu UeharaShozo YanagidaChyongjin Pac
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1990 Volume 19 Issue 8 Pages 1339-1342

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Abstract

The isomerization of Hexamethyl(Dewar benzene) to hexamethylbenzene is photosensitized by 1,4-dicyanonaphthalenearene exciplexes. Spectroscopic and quantum-yield studies suggest that the isomerization proceeds mostly through an adiabatic pathway from hypothetical termolecular excited complexes (triplexes).

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© 1990 The Chemical Society of Japan
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