Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Selective Synthesis of (Z)-1-Ethylidene-2-silylcycloalkanes by Palladium-Catalyzed Hydrosilylation of 1-Vinylcycloalkenes
Tamio HayashiSunantha HengrasmeeYonetatsu Matsumoto
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1990 Volume 19 Issue 8 Pages 1377-1380

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Abstract

Hydrosilylation of 1-vinylcycloalkenes with methyldichlorosilane in the presence of a palladium catalyst proceeded with high regio- and stereoselectivity to give (Z)-1-ethylidene-2-silylcycloalkanes in high yields.

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© 1990 The Chemical Society of Japan
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