Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Nitrosation of α,β-Unsaturated Carboxamide with Nitric Oxide and Triethylsilane Catalyzed by Cobalt(II) Complex
Koji KatoTeruaki Mukaiyama
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1990 Volume 19 Issue 8 Pages 1395-1398

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Abstract

In the presence of a catalytic amount of N,N′-bis(2-ethoxycarbonyl-3-oxobutylidene)ethylenediaminatocobalt(II), various α,β-unsaturated carboxamides are converted to the corresponding 2-nitrosocarboxamides regioselectively in good yields on treatment with nitric oxide and triethylsilane at room temperature.

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© 1990 The Chemical Society of Japan
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