Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A Novel Synthesis of Primary Selenoamides from Nitriles by the Treatment of Bis(trimethylsilyl) Selenide and BF3·OEt2
Kazuaki ShimadaShigeki HikageYoshiyuki TakeishiYuji Takikawa
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1990 Volume 19 Issue 8 Pages 1403-1406

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Abstract

Reaction of nitriles with (Me3Si)2 Se in the presence of BF3·OEt2 afforded the corresponding primary selenoamides in moderate yields. A selenourea and a selenothiocarbamate were also prepared in a similar manner from the corresponding cyanamide and thiocyanate.

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© 1990 The Chemical Society of Japan
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