Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
A Facile Synthesis of 3-Deoxy-α-D-manno-2-octulopyranosides Using Pyridinium p-Toluenesulfonate
Shigeomi HoritoMuneo TadaHironobu Hashimoto
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1991 Volume 20 Issue 1 Pages 117-120

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Abstract

A new method of ketosidation was developed using 4,5:7,8-di-O-isopropylidenated 3-deoxy-D-manno-2-octulose and its 1-O-protected derivatives as ketosyl donors in the presence of pyridinium p-toluenesulfonate to afford the α-ketoside exclusively.

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© 1991 The Chemical Society of Japan
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